2.2. Modes
765 Dosimat
14
The formulae for calculation of the volume to be dispensed "add V" are shown in the
following table, with
cnt content in the selected unit
M molar mass of substance to be weighed out
f factor
dens density of the solvent
s weight of substance
Unit Formula for
add V =
Amount-of-substance
concentration
mol/L
mmol/L
f·s·10
3
cnt·M
f·s·10
6
cnt·M
Mass concentration
g/L
mg/L
f·s·10
3
cnt
f·s·10
6
cnt
Mass fraction
%
ppm
f·s(10
2
-cnt)
cnt·dens
f·s(10
6
-cnt)
cnt dens
Molality
mol/kg
mmol/kg
s·10
3
cnt·M·dens
s·10
6
cnt·M·dens
Application of factor f
Factor f for ionic standards
With ionic standards, the mass fraction of a single ion A is usually specified. On the other
hand, the solution is prepared from A
n
B
m
, e.g. a standard of 10 ppm Pb
2+
prepared from
Pb(NO
3
)
2
. The factor f is calculated from the formula:
n*M(A) m*M(B)
f = ———— or f = ————
M(A
n
B
m
) M(A
n
B
m
)
M(A): molar mass of ion A
M(B): molar mass of ion B
M(A
n
B
m
): molar mass of substance A
n
B
m
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